Direct Synthesis of Metal Complexes Book

Direct Synthesis of Metal Complexes


  • Author : B.I. Kharisov
  • Publisher : Elsevier
  • Release Date : 2018-04-19
  • Genre: Science
  • Pages : 468
  • ISBN 10 : 9780128110621

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Direct Synthesis of Metal Complexes Excerpt :

Direct Synthesis of Metal Complexes provides in-depth coverage of the direct synthesis of coordination and organometallic compounds. The work is primarily organized by methods, but also covers highly relevant complexes, such as metal-polymer coordination compounds. This updated reference discusses recent developments in cryosynthesis, electrosynthesis, and tribosynthesis (popular as it doesn’t require organic solvents), with special attention paid to ‘greener’ methodologies and approaches. Additionally, the book describes physical methods of zero-valent metal interaction with organic matter, including sputtering, ultrasonic treatment and synthesis in ionic liquids. The book presents completely new content as a follow-up to the 1999 Elsevier Science publication Direct Synthesis of Coordination and Organometallic Compounds that was edited by Dr. Garnovskii and Dr. Kharisov. Covers current methods and techniques of metal interactions with organic media leading to metal chelates, adducts, di- and polymetallic complexes, metal-containing macrocycles, supported coordination compounds (i.e., metal complexes on carbon nanotubes), and more Describes reactivities of distinct forms of elemental metals (powders, sheets, nanoparticles (including a host of less-common metal nanostructures) with organic phase (liquid, solid and gaseous) and water Includes experimental procedures, with examples of direct synthesis, at the end of each chapter

Direct Synthesis of Coordination and Organometallic Compounds Book

Direct Synthesis of Coordination and Organometallic Compounds


  • Author : A.D. Garnovskii
  • Publisher : Elsevier
  • Release Date : 1999-08-13
  • Genre: Science
  • Pages : 244
  • ISBN 10 : 0080530443

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Direct Synthesis of Coordination and Organometallic Compounds Excerpt :

This book is devoted to the interaction between elemental metals and (in)organic ligands in different reaction conditions. Metals could be activated for further reactions as cryosynthesis, electrosynthesis and tribosynthesis, some of them with or without ultrasonic and microwave treatment. The kinetics of metal dissolution in various non-aqueous media is discussed in detail. Many methods are used nowadays to synthesize coordination compounds. Metal complexes are obtained mainly by the direct interaction of the components (the ligands and a source of the complex-forming metal), as a result of ligand and metal exchange, and under the conditions of template synthesis, which also include the method of nascent reagents. In these methods the source of the metal is either its salts or carbonyls. At the same time, it has long been known that coordination compounds may be obtained as a result of direct synthesis from zero-valent metals. Methods for the synthesis of complex compounds under the conditions of gas-phase reactions, oxidative dissolution of zero-valent metals in non-aqueous media, and in the solid phase have been developed. These methods have become the basis of a new field in synthetic chemistry - the direct synthesis of coordination and organometallic compounds from zero-valent metals. Particular aspects of the above problem have been described in a series of reviews and monographs. However, on the whole these main parts of the direct synthesis of metal complexes has not been dealt with in the review and monograph publications on coordination chemistry. So, the main objective of this book is to analyze, discuss and generalize the existing information in the area of direct reactions leading to the coordination and organometallic reactions. Some methods of direct synthesis have been developed in the former USSR (in particular, a lot of works on cryosynthesis, pioneered (1972-1973) and recent works on electrosynthesis) but, in spite of their novelty and/or wide app

Pincer Compounds Book

Pincer Compounds


  • Author : David Morales-Morales
  • Publisher : Elsevier
  • Release Date : 2018-04-11
  • Genre: Science
  • Pages : 754
  • ISBN 10 : 9780128129326

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Pincer Compounds Excerpt :

Pincer Compounds: Chemistry and Applications offers valuable state-of-the-art coverage highlighting highly active areas of research—from mechanistic work to synthesis and characterization. The book focuses on small molecule activation chemistry (particularly H2 and hydrogenation), earth abundant metals (such as Fe), actinides, carbene-pincers, chiral catalysis, and alternative solvent usage. The book covers the current state of the field, featuring chapters from renowned contributors, covering four continents and ranging from still-active pioneers to new names emerging as creative strong contributors to this fascinating and promising area. Over a decade since the publication of Morales-Morales and Jensen’s The Chemistry of Pincer Compounds (Elsevier 2007), research in this unique area has flourished, finding a plethora of applications in almost every single branch of chemistry—from their traditional application as very robust and active catalysts all the way to potential biological and pharmaceutical applications. Describes the chemistry and applications of this important class of organometallic and coordination compounds Includes contributions from global leaders in the field, featuring pioneers in the area as well as emerging experts conducting exciting research on pincer complexes Highlights areas of promising and active research, including small molecule activation, earth abundant metals, and actinide chemistry

Transition Metal Organometallics in Organic Synthesis Book

Transition Metal Organometallics in Organic Synthesis


  • Author : Howard Alper
  • Publisher : Academic Press
  • Release Date : 2016-01-21
  • Genre: Science
  • Pages : 200
  • ISBN 10 : 9781483215921

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Transition Metal Organometallics in Organic Synthesis Excerpt :

Transition Metal Organometallics in Organic Synthesis, Volume II covers chapters on the applications of arene and alkyne complexes, as well as cluster compounds, in organic synthesis. The book discusses the potential utility of transition metal-alkyne complexes and derived cluster compounds as reagents in organic synthesis, as well as the complexation reactions of arenes. The text also describes the oxidation, reduction, rearrangement, and other synthetically useful processes. Chemists will find the book invaluable.

The Chemistry of Pincer Compounds Book

The Chemistry of Pincer Compounds


  • Author : David Morales-Morales
  • Publisher : Elsevier
  • Release Date : 2011-08-11
  • Genre: Science
  • Pages : 466
  • ISBN 10 : 0080545157

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The Chemistry of Pincer Compounds Excerpt :

Pincer complexes are formed by the binding of a chemical structure to a metal atom with at least one carbon-metal bond. Usually the metal atom has three bonds to a chemical backbone, enclosing the atom like a pincer. The resulting structure protects the metal atom and gives it unique properties. The last decade has witnessed the continuous growth in the development of pincer complexes. These species have passed from being curiosity compounds to chemical chameleons able to perform a wide variety of applications. Their unique metal bound structures provide some of the most active catalysts yet known for organic transformations involving the activation of bonds. The Chemistry of Pincer Compounds details use of pincer compounds including homogeneous catalysis, enantioselective organic transformations, the activation of strong bonds, the biological importance of pincer compounds as potential therapeutic or pharmaceutical agents, dendrimeric and supported materials. * Describes the chemistry and applications of this important class of organometallic and coordination compounds * Covers the areas in which pincer complexes have had an impact * Includes information on more recent and interesting pincer compounds not just those that are well-known

Synthesis of Pesticides Chemical Structure and Biological Activity Natural Products with Biological Activity Book

Synthesis of Pesticides Chemical Structure and Biological Activity Natural Products with Biological Activity


  • Author : H. Geissbühler
  • Publisher : Elsevier
  • Release Date : 2013-10-22
  • Genre: Technology & Engineering
  • Pages : 348
  • ISBN 10 : 9781483278513

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Synthesis of Pesticides Chemical Structure and Biological Activity Natural Products with Biological Activity Excerpt :

Advances in Pesticide Science, Part 2: Synthesis of Pesticides, Chemical Structure and Biological Activity, Natural Products with Biological Activity is a collection of papers presented at the Fourth International Congress of Pesticide Chemistry, held in Zurich, Switzerland on July 24-28, 1978. This book is composed of forty eight chapters, and begins with the synthesis of pesticides. The succeeding chapters deal with heterocyclic synthesis by rearrangement, synthesis and transformations of nitrogen and sulphurcontaining bicyclic heterocyclic systems. These topics are followed by discussions on synthesis of bmc-analogous n-heterocycles from 1,2-, 1,3-, 1,4-, and 1,5- diamines. Other chapters describe the synthesis and herbicidal activity of 4-acylpyrazole derivatives, the synthesis and properties of plant growth regulators, the carboxyphenyl derivatives of five and six membered heterocycles and potential phosphorus-containing intermediates for the synthesis of pesticides. The final chapters consider the influence of antagonistic fungi on the spore-formation of rust fungi. This book will prove useful to agriculturists and organic chemists.

Synthetic Coordination and Organometallic Chemistry Book

Synthetic Coordination and Organometallic Chemistry


  • Author : Alexander D. Garnovskii
  • Publisher : CRC Press
  • Release Date : 2003-04-25
  • Genre: Science
  • Pages : 520
  • ISBN 10 : 0203911520

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Synthetic Coordination and Organometallic Chemistry Excerpt :

This reference describes standard and nonstandard coordination modes of ligands in complexes, the intricacies of polyhedron-programmed and regioselective synthesis, and the controlled creation of coordination compounds such as molecular and hn-p-complexes, chelates, and homo- and hetero-nuclear compounds. It offers a clear and concise review of modern synthetic techniques of metal complexes as well as lesser known gas- and solid-phase synthesis, electrosynthesis, and microwave and ultrasonic treatment of the reaction system. The authors pay special attention to o-hydroxyazomethines and their S-, Se-containing analogues, b-diketones, and quinines, among others, and examine the immediate interaction of ligands and metal salts or carbonyls.

Transition metal Organometallics In Organic Synthesis Book

Transition metal Organometallics In Organic Synthesis


  • Author : Howard Alper
  • Publisher : Elsevier
  • Release Date : 2012-12-02
  • Genre: Science
  • Pages : 270
  • ISBN 10 : 9780323161930

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Transition metal Organometallics In Organic Synthesis Excerpt :

Transition Metal Organometallics in Organic Synthesis: Volume I reviews the literature in the field of organic synthesis with a focus on the most effective synthetic transformations. The text covers topics such as the general considerations in organic synthesis, C-C and C-X bond formations, and the isomerization and reorganization reactions of olefins. Also covered are topics such as displacement reactions with transition metal complexes, electrophilic reactions of organopalladium complexes, carbonylation reactions, and metal-carbene complexes — its structure, spectra, bonding, and direct synthesis. The book is recommended as a reference for chemists and inorganic chemists who would like to learn the applications of organometallic complexes as reagents and catalysts.

Deuteride Materials Book

Deuteride Materials


  • Author : Jiping Liu
  • Publisher : Springer
  • Release Date : 2019-02-27
  • Genre: Science
  • Pages : 289
  • ISBN 10 : 9789811369629

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Deuteride Materials Excerpt :

This is the very first book that offers an up-to-date and comprehensive overview on deuteride. It not only includes the concept, existing forms, key characteristics, but also reviews the preparation and characterization technologies and the latest research developments of deuteride. The special properties such as the nuclear properties, isotropic and neutron effect, poisonousness, radioactivity, volume expansion are systematically discussed to build up the sound understanding of the materials. In particular, this work reviews a number of commercial and scientific uses of the materials including nuclear reactors, NMR spectroscopy and medicines. Researchers and industrial professionals in medicine, chemistry, biochemistry, environmental sciences and defense sciences will benefit from this work.

Clathrochelates Book

Clathrochelates


  • Author : Y.Z. Voloshin
  • Publisher : Elsevier
  • Release Date : 2002-09-19
  • Genre: Science
  • Pages : 432
  • ISBN 10 : 9780080529172

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Clathrochelates Excerpt :

Clathrochelates are compounds which contain a metal ion encapsulated within a three dimensional cage of macrobicyclic ligand atoms. Within this cage the metal has unique properties and is to a great extent isolated from environmental factors. Such complexes are suitable as models of the most essential biological systems, membrane transport, electron carriers, highly selective and sensitive analytical reagents, catalysts for photochemical and redox processes, cation and anion receptors, etc. The aim of this monograph is to generalize and analyze experimental and theoretical data on clathrochelates in order to promote further research in this promising field of chemistry. Chapter 1 gives general concepts of complexes with encapsulated metal ions, discusses basic specific features of these compounds, considers and characterizes the main types of compounds with encapsulated metal ions and the main classes of clathrochelates, and includes the current nomenclature. Chapter 2 deals with the pathways of clathrochelate synthesis and the general procedures for the synthesis of macrobicyclic tris-dioximates, phosphorus-containing tris-diiminates, sepulchrates, sarcophagi-nates, and polyene and other types of clathrochelate complexes. Chapter 3 concerns studies of the electronic and spatial structure of clathrochelate complexes. In Chapter 4, the kinetics and mechanism of synthesis and decomposition reactions of macrobicyclic tris-dioximates, sarcophaginates, and sepulchrates in solution and gas phases are discussed. Chapter 5 considers the electrochemical, photochemical, and some other characteristics of clathrochelates and their applications associated with these characteristics. Finally, the practical applications of the unique properties of clathrochelates and perspectives on the synthesis of new clathrochelates are described in Chapters 6 and 7, respectively.

Molecular Electrochemistry of Inorganic  Bioinorganic and Organometallic Compounds Book

Molecular Electrochemistry of Inorganic Bioinorganic and Organometallic Compounds


  • Author : A.J.L. Pombeiro
  • Publisher : Springer Science & Business Media
  • Release Date : 2012-02-02
  • Genre: Science
  • Pages : 667
  • ISBN 10 : 9789401116282

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Molecular Electrochemistry of Inorganic Bioinorganic and Organometallic Compounds Excerpt :

The use of electrochemical techniques by chemists, particularly those who regard themselves as "inorganic" coordination chemists, has undergone a very rapid growth in the last 15-20 years. The techniques, as dassically applied to inorganic species, had their origins in analytical chemistry, and the methodology had assumed, until the mid 60s, more importance than the chemiStry. However, the growth of interest in coordination compounds (including organometallic complexes) having unusually rich of electron-transfer in bio-inorganic redox properties, and in the understanding species, has propelfed electro-chemistry into the foreground of potentially readily available techniques for application to a very wide range of problems of interest to those chemists. This growth has been fuelled additionally by the availability of relatively cheap equipment of growing sophistication and by an increase in the "inorganic" chemists' general knowledge of physical electrochemistry. In particular, with increasing availability and sophistication of eqUipment, kinetic problems are now being addressed, and the range of electrode types and configuration and solvents has been greatly expanded. Furthermore, the rapid expansion of interest in biological problems has opened new avenues in functionalisation of electrodes, in the development of sensory devices and, in a sense, a return to the analytical base of the science, using novel and multi-disciplinary techniques drawing on synthesis chemistry of and electronic micro-engeneering. The drive towards increasing use microcomputer-controlled data analysis and the development of microeledrodes has opened exciting new avenues for the exploration of chemical reactions involving electron-transfer processes.

Russian Chemical Reviews Book

Russian Chemical Reviews


  • Author : Anonim
  • Publisher : Unknown
  • Release Date : 2005
  • Genre: Chemistry
  • Pages : null
  • ISBN 10 : UOM:39015059042542

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Russian Chemical Reviews Excerpt :

Inorganic Synthesis Book

Inorganic Synthesis


  • Author : Nikolay Gerasimchuk
  • Publisher : Cambridge Scholars Publishing
  • Release Date : 2019-10-24
  • Genre: Juvenile Nonfiction
  • Pages : 396
  • ISBN 10 : 9781527542143

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Inorganic Synthesis Excerpt :

This book is designed to develop important practical skills for chemistry majors interested in synthetic chemistry. It will serve to teach students proper techniques for the preparation and handling of a variety of inorganic and coordination compounds. It shows them how to conduct thermal decomposition reactions; prepare moderately air-sensitive and moisture-sensitive compounds; and characterise obtained metal complexes using a variety of physical methods. This volume is well-illustrated with colour photos, schemes and figures that allow safe, step-by-step work on assigned laboratory experiments. There are extensive pre-lab instructions for techniques, concepts and topics of experiments, and complete initial introductions to the methods used during the lab are also provided. Because of its clearly presented content with numerous practical examples, this book will be of great interest to chemistry professionals working in industry.

Handbook on Applications of Ultrasound Book

Handbook on Applications of Ultrasound


  • Author : Dong Chen
  • Publisher : CRC Press
  • Release Date : 2011-07-26
  • Genre: Science
  • Pages : 739
  • ISBN 10 : 9781439842072

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Handbook on Applications of Ultrasound Excerpt :

Ultrasonic irradiation and the associated sonochemical and sonophysical effects are complementary techniques for driving more efficient chemical reactions and yields. Sonochemistry—the chemical effects and applications of ultrasonic waves—and sustainable (green) chemistry both aim to use less hazardous chemicals and solvents, reduce energy consumption, and increase product selectivity. A comprehensive collection of knowledge, Handbook on Applications of Ultrasound covers the most relevant aspects linked to and linking green chemistry practices to environmental sustainability through the uses and applications of ultrasound-mediated and ultrasound-assisted biological, biochemical, chemical, and physical processes. Chapters are presented in the areas of: Medical applications Drug and gene delivery Nanotechnology Food technology Synthetic applications and organic chemistry Anaerobic digestion Environmental contaminants degradation Polymer chemistry Industrial syntheses and processes Reactor design Electrochemical systems Combined ultrasound−microwave technologies While the concepts of sonochemistry have been known for more than 80 years, in-depth understanding of this phenomenon continues to evolve. Through a review of the current status of chemical and physical science and engineering in developing more environmentally friendly and less toxic synthetic processes, this book highlights many existing applications and the enormous potential of ultrasound technology to upgrade present industrial, agricultural, and environmental processes.