Palladacycles Book

Palladacycles


  • Author : Jairton Dupont
  • Publisher : John Wiley & Sons
  • Release Date : 2008-10-13
  • Genre: Science
  • Pages : 417
  • ISBN 10 : 9783527317813

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Palladacycles Excerpt :

From synthesis to applications in catalysis, material science and biology this much-needed book is the first to comprehensively present everything you need to know about palladacycles. Renowned international authors guarantee high-quality content, making this a must-have for everyone working in the field.

Palladacycles Book

Palladacycles


  • Author : Anant Kapdi
  • Publisher : Elsevier
  • Release Date : 2019-06-14
  • Genre: Science
  • Pages : 420
  • ISBN 10 : 9780128165164

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Palladacycles Excerpt :

Palladacycles: Catalysis and Beyond provides an overview of recent research in palladacycles in catalysis for cross-coupling and similar reactions. In the quest for developing highly efficient and robust palladium-based catalysts for C-C bond formation via cross-coupling reactions, palladacycles have played a significant role. In recent years, they have found a wide variety of applications, ranging from catalysts for cross-coupling and related reactions, to their more recent application as anticancer agents. This book explores early examples of the use of palladacyclic complexes in catalysis employing azobenzene and hydrazobenzene as coordinating ligands. Its applications in processes such as selective reduction of alkenes, alkynes, or nitroalkanes are also covered. Palladacycles: Catalysis and Beyond reveals the tremendous advances that have taken place in the potential applications of palladacycles as versatile catalysts in academia and industry. It is a valuable resource for synthetic chemists, organometallic chemists, and chemical biologists. Reviews the importance and various applications of palladacycles in academic research and industry, including industrial scale applications Includes the impact of palladacycles on coupling reactions and potential applications as anticancer agents Features coverage of nano and colloidal catalysis via palladacyclic degradation

Pincer Compounds Book

Pincer Compounds


  • Author : David Morales-Morales
  • Publisher : Elsevier
  • Release Date : 2018-04-11
  • Genre: Science
  • Pages : 754
  • ISBN 10 : 9780128129326

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Pincer Compounds Excerpt :

Pincer Compounds: Chemistry and Applications offers valuable state-of-the-art coverage highlighting highly active areas of research—from mechanistic work to synthesis and characterization. The book focuses on small molecule activation chemistry (particularly H2 and hydrogenation), earth abundant metals (such as Fe), actinides, carbene-pincers, chiral catalysis, and alternative solvent usage. The book covers the current state of the field, featuring chapters from renowned contributors, covering four continents and ranging from still-active pioneers to new names emerging as creative strong contributors to this fascinating and promising area. Over a decade since the publication of Morales-Morales and Jensen’s The Chemistry of Pincer Compounds (Elsevier 2007), research in this unique area has flourished, finding a plethora of applications in almost every single branch of chemistry—from their traditional application as very robust and active catalysts all the way to potential biological and pharmaceutical applications. Describes the chemistry and applications of this important class of organometallic and coordination compounds Includes contributions from global leaders in the field, featuring pioneers in the area as well as emerging experts conducting exciting research on pincer complexes Highlights areas of promising and active research, including small molecule activation, earth abundant metals, and actinide chemistry

Catalyzed Mizoroki   Heck Reaction or C   H activation Book

Catalyzed Mizoroki Heck Reaction or C H activation


  • Author : Sabine Berteina-Raboin
  • Publisher : MDPI
  • Release Date : 2020-02-13
  • Genre: Technology & Engineering
  • Pages : 182
  • ISBN 10 : 9783039281381

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Catalyzed Mizoroki Heck Reaction or C H activation Excerpt :

In the last few decades, research on the elaboration by palladium-catalytic processes of C-C bonds or the activation of C–H bonds has increased considerably. Yet there is still room for much improvement in terms of selectivity, or enantioselectivity, via the development of new ligands or the study of the catalytic effect of other metals to carry out the same chemical transformations. In addition, the attention paid to environmentally friendly methods in terms of the quantities of catalysts, ligands, and solvents is currently indispensable. The Mizoroki-Heck reaction is one of these important catalytic methods which generates C-C bonds in organic synthesis and is also possible by C-H activation. This book, titled “Catalyzed Mizoroki-Heck Reaction or C-H activation” focuses on new advances in the formation of C-C bonds or new C-H activation methods. It contains original research papers and short reviews on the synthesis of biologically active compounds using these catalytic processes, the identification of new catalysts, of new conditions allowing selectivity or enantioselectivity, the activity and stability of catalyst under turnover conditions, and all improvements in catalytic processes.

Strategies for Palladium Catalyzed Non directed and Directed C H Bond Functionalization Book

Strategies for Palladium Catalyzed Non directed and Directed C H Bond Functionalization


  • Author : Anant R. Kapdi
  • Publisher : Elsevier
  • Release Date : 2017-06-23
  • Genre: Science
  • Pages : 500
  • ISBN 10 : 9780128052556

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Strategies for Palladium Catalyzed Non directed and Directed C H Bond Functionalization Excerpt :

Strategies for Palladium-Catalyzed Non-directed and Directed C-H Bond Functionalization portrays the complete scope of these two aspects of C-H bond functionalization in a single volume for the first time. Featured topics include the influence of palladacyclic systems in C-H bond functionalization (need for newer catalytic systems for better efficiency), mechanistic aspect of the functionalization strategies leading to better systems, and applications of these methodologies to natural product synthesis and material synthesis. Addresses the involvement of catalytic systems (palladacycles) for better functionalization of (hetero)arenes to emphasize the need for developing better, more selective systems Covers the use of powerful mechanistic tools for understanding and assisting the development of better functionalization strategies Discusses the finer aspects of C-H bond functionalization, such as control of regioselectivity with or without directing groups Includes a chapter detailing the synthesis of naturally occurring molecules or functional molecules via both pathways for assessing the applicability of the functionalization strategies

Modern Alkyne Chemistry Book

Modern Alkyne Chemistry


  • Author : Barry M. Trost
  • Publisher : John Wiley & Sons
  • Release Date : 2015-02-09
  • Genre: Science
  • Pages : 424
  • ISBN 10 : 9783527335053

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Modern Alkyne Chemistry Excerpt :

A comprehensive and up-to-date overview of alkyne chemistry, taking into account the progress made over the last two decades. The experienced editors are renowned world leaders in the field, while the list of contributors reads like a "Who's Who" of synthetic organic chemistry. The result is a valuable reference not only for organic chemists at universities and in the chemical industry, but also for biologists and material scientists involved in the modern synthesis of organic compounds and materials.

The Mizoroki Heck Reaction Book

The Mizoroki Heck Reaction


  • Author : Martin Oestreich
  • Publisher : John Wiley & Sons
  • Release Date : 2009-02-11
  • Genre: Science
  • Pages : 608
  • ISBN 10 : 0470716061

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The Mizoroki Heck Reaction Excerpt :

Exploring the importance of Richard F. Heck’s carbon coupling reaction, this book highlights the subject of the 2010 Nobel Prize in Chemistry for palladium-catalyzed cross couplings in organic synthesis, and includes a foreword from Nobel Prize winner Richard F. Heck. The Mizoroki-Heck reaction is a palladium-catalyzed carbon–carbon bond forming process which is widely used in organic and organometallic synthesis. It has seen increasing use in the past decade as chemists look for strategies enabling the controlled construction of complex carbon skeletons. The Mizoroki-Heck Reaction is the first dedicated volume on this important reaction, including topics on: mechanisms of the Mizoroki-Heck reaction intermolecular Mizoroki-Heck reactions focus on regioselectivity and product outcome in organic synthesis waste-minimized Mizoroki-Heck reactions intramolecular Mizoroki-Heck reactions formation of heterocycles chelation-controlled Mizoroki-Heck reactions the Mizoroki-Heck reaction in domino processes oxidative heck-type reactions (Fujiwara-Moritani reactions) Mizoroki-Heck reactions with metals other than palladium ligand design for intermolecular asymmetric Mizoroki-Heck reactions intramolecular enantioselective Mizoroki-Heck reactions desymmetrizing Mizoroki-Heck reactions applications in combinatorial and solid phase syntheses, and the development of modern solvent systems and reaction techniques the asymmetric intramolecular Mizoroki-Heck reaction in natural product total synthesis Several chapters are devoted to asymmetric Heck reactions with particular focus on the construction of otherwise difficult-to-obtain sterically congested tertiary and quaternary carbons. Industrial and academic applications are highlighted in the final section. The Mizoroki-Heck Reaction will find a place on the bookshelves of any organic or organometallic chemist. “I am convinced that this book will rapidly become the most important reference text for research chemists in academia

Organophosphorus Compounds   Advances in Research and Application  2013 Edition Book

Organophosphorus Compounds Advances in Research and Application 2013 Edition


  • Author : Anonim
  • Publisher : ScholarlyEditions
  • Release Date : 2013-06-21
  • Genre: Science
  • Pages : 495
  • ISBN 10 : 9781481678506

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Organophosphorus Compounds Advances in Research and Application 2013 Edition Excerpt :

Organophosphorus Compounds—Advances in Research and Application: 2013 Edition is a ScholarlyEditions™ book that delivers timely, authoritative, and comprehensive information about Phosphonic Acids. The editors have built Organophosphorus Compounds—Advances in Research and Application: 2013 Edition on the vast information databases of ScholarlyNews.™ You can expect the information about Phosphonic Acids in this book to be deeper than what you can access anywhere else, as well as consistently reliable, authoritative, informed, and relevant. The content of Organophosphorus Compounds—Advances in Research and Application: 2013 Edition has been produced by the world’s leading scientists, engineers, analysts, research institutions, and companies. All of the content is from peer-reviewed sources, and all of it is written, assembled, and edited by the editors at ScholarlyEditions™ and available exclusively from us. You now have a source you can cite with authority, confidence, and credibility. More information is available at http://www.ScholarlyEditions.com/.

Cyclometalation Reactions Book

Cyclometalation Reactions


  • Author : Iwao Omae
  • Publisher : Springer Science & Business Media
  • Release Date : 2014-01-23
  • Genre: Science
  • Pages : 208
  • ISBN 10 : 9784431546047

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Cyclometalation Reactions Excerpt :

This book provides a review of cyclometalation reactions and organometallic intramolecular-coordination five-membered ring products, the most active type of reactions in synthetic organic reactions and their products. Included is the discovery of intramolecular-coordination bonds in cyclometalation reactions and the characteristics of those reactions, as well as the reasons that their five-membered ring compounds are very easily synthesized through such reactions. In addition, the applications of cyclometalation reactions and five-membered ring products, synthetic applications, catalysts, and other products are described. These topics are of special interest for industrial researchers.

Suzuki   Miyaura Cross  Coupling Reaction and Potential Applications Book

Suzuki Miyaura Cross Coupling Reaction and Potential Applications


  • Author : Ioannis D. Kostas
  • Publisher : MDPI
  • Release Date : 2018-03-23
  • Genre: Science
  • Pages : 272
  • ISBN 10 : 9783038425564

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Suzuki Miyaura Cross Coupling Reaction and Potential Applications Excerpt :

This book is a printed edition of the Special Issue "Suzuki–Miyaura Cross-Coupling Reaction and Potential Applications" that was published in Catalysts

Modern Arylation Methods Book

Modern Arylation Methods


  • Author : Lutz Ackermann
  • Publisher : John Wiley & Sons
  • Release Date : 2009-04-22
  • Genre: Science
  • Pages : 561
  • ISBN 10 : 9783527627332

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Modern Arylation Methods Excerpt :

Today, arylation methods are belonging to the most important reaction types in organic synthesis. Lutz Ackermann, a young and ambitious professor has gathered a number of top international authors to present the first comprehensive book on the topic. Starting from a historical review, the book covers hot topics like Palladium-catalyzed arylation of N-H and alpha-C-H-acidic Bonds, Copper-catalyzed arylation of N-H and O-H Bonds, direct arylation reactions, carbanion aromatic synthesis, arylation reactions of alkenes, alkynes and much more. This compact source of high quality information is indispensable to synthetic chemists and those working in the pharmaceutical and chemical industry.

New Trends in Cross Coupling Book

New Trends in Cross Coupling


  • Author : Thomas Colacot
  • Publisher : Royal Society of Chemistry
  • Release Date : 2014-10-27
  • Genre: Science
  • Pages : 912
  • ISBN 10 : 9781849738965

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New Trends in Cross Coupling Excerpt :

Following on from its recognition in the 2010 Nobel Prize for Chemistry, contributors from across the globe present the latest cross-coupling trends in both academia and industry.

Comprehensive Organic Synthesis Book

Comprehensive Organic Synthesis


  • Author : Anonim
  • Publisher : Newnes
  • Release Date : 2014-02-14
  • Genre: Science
  • Pages : 9806
  • ISBN 10 : 9780080977430

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Comprehensive Organic Synthesis Excerpt :

The second edition of Comprehensive Organic Synthesis—winner of the 2015 PROSE Award for Multivolume Reference/Science from the Association of American Publishers—builds upon the highly respected first edition in drawing together the new common themes that underlie the many disparate areas of organic chemistry. These themes support effective and efficient synthetic strategies, thus providing a comprehensive overview of this important discipline. Fully revised and updated, this new set forms an essential reference work for all those seeking information on the solution of synthetic problems, whether they are experienced practitioners or chemists whose major interests lie outside organic synthesis. In addition, synthetic chemists requiring the essential facts in new areas, as well as students completely new to the field, will find Comprehensive Organic Synthesis, Second Edition an invaluable source, providing an authoritative overview of core concepts. Winner of the 2015 PROSE Award for Multivolume Reference/Science from the Association of American Publishers Contains more than170 articles across nine volumes, including detailed analysis of core topics such as bonds, oxidation, and reduction Includes more than10,000 schemes and images Fully revised and updated; important growth areas—including combinatorial chemistry, new technological, industrial, and green chemistry developments—are covered extensively

The Chemistry of Pincer Compounds Book

The Chemistry of Pincer Compounds


  • Author : David Morales-Morales
  • Publisher : Elsevier
  • Release Date : 2011-08-11
  • Genre: Science
  • Pages : 466
  • ISBN 10 : 0080545157

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The Chemistry of Pincer Compounds Excerpt :

Pincer complexes are formed by the binding of a chemical structure to a metal atom with at least one carbon-metal bond. Usually the metal atom has three bonds to a chemical backbone, enclosing the atom like a pincer. The resulting structure protects the metal atom and gives it unique properties. The last decade has witnessed the continuous growth in the development of pincer complexes. These species have passed from being curiosity compounds to chemical chameleons able to perform a wide variety of applications. Their unique metal bound structures provide some of the most active catalysts yet known for organic transformations involving the activation of bonds. The Chemistry of Pincer Compounds details use of pincer compounds including homogeneous catalysis, enantioselective organic transformations, the activation of strong bonds, the biological importance of pincer compounds as potential therapeutic or pharmaceutical agents, dendrimeric and supported materials. * Describes the chemistry and applications of this important class of organometallic and coordination compounds * Covers the areas in which pincer complexes have had an impact * Includes information on more recent and interesting pincer compounds not just those that are well-known