Pincer Compounds Book

Pincer Compounds


  • Author : David Morales-Morales
  • Publisher : Elsevier
  • Release Date : 2018-04-11
  • Genre: Science
  • Pages : 754
  • ISBN 10 : 9780128129326

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Pincer Compounds Excerpt :

Pincer Compounds: Chemistry and Applications offers valuable state-of-the-art coverage highlighting highly active areas of research—from mechanistic work to synthesis and characterization. The book focuses on small molecule activation chemistry (particularly H2 and hydrogenation), earth abundant metals (such as Fe), actinides, carbene-pincers, chiral catalysis, and alternative solvent usage. The book covers the current state of the field, featuring chapters from renowned contributors, covering four continents and ranging from still-active pioneers to new names emerging as creative strong contributors to this fascinating and promising area. Over a decade since the publication of Morales-Morales and Jensen’s The Chemistry of Pincer Compounds (Elsevier 2007), research in this unique area has flourished, finding a plethora of applications in almost every single branch of chemistry—from their traditional application as very robust and active catalysts all the way to potential biological and pharmaceutical applications. Describes the chemistry and applications of this important class of organometallic and coordination compounds Includes contributions from global leaders in the field, featuring pioneers in the area as well as emerging experts conducting exciting research on pincer complexes Highlights areas of promising and active research, including small molecule activation, earth abundant metals, and actinide chemistry

The Chemistry of Pincer Compounds Book

The Chemistry of Pincer Compounds


  • Author : David Morales-Morales
  • Publisher : Elsevier
  • Release Date : 2011-08-11
  • Genre: Science
  • Pages : 466
  • ISBN 10 : 0080545157

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The Chemistry of Pincer Compounds Excerpt :

Pincer complexes are formed by the binding of a chemical structure to a metal atom with at least one carbon-metal bond. Usually the metal atom has three bonds to a chemical backbone, enclosing the atom like a pincer. The resulting structure protects the metal atom and gives it unique properties. The last decade has witnessed the continuous growth in the development of pincer complexes. These species have passed from being curiosity compounds to chemical chameleons able to perform a wide variety of applications. Their unique metal bound structures provide some of the most active catalysts yet known for organic transformations involving the activation of bonds. The Chemistry of Pincer Compounds details use of pincer compounds including homogeneous catalysis, enantioselective organic transformations, the activation of strong bonds, the biological importance of pincer compounds as potential therapeutic or pharmaceutical agents, dendrimeric and supported materials. * Describes the chemistry and applications of this important class of organometallic and coordination compounds * Covers the areas in which pincer complexes have had an impact * Includes information on more recent and interesting pincer compounds not just those that are well-known

Advances in Organometallic Chemistry Book

Advances in Organometallic Chemistry


  • Author : Pedro J. Perez
  • Publisher : Academic Press
  • Release Date : 2020-03-03
  • Genre: Science
  • Pages : 314
  • ISBN 10 : 9780128206911

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Advances in Organometallic Chemistry Excerpt :

Advances in Organometallic Chemistry, Volume 73, the latest release in this longstanding serial, is known for its comprehensive coverage of topics in organometallic synthesis, reactions, mechanisms, homogeneous catalysis, and more. It is ideal for a wide range of researchers involved in organometallic chemistry, including synthetic protocols, mechanistic studies and practical applications. Specific chapters in this new release include Metal carbonyl promoted multicomponent coupling of alkyne for synthesis of heterocyclic compounds, Group 10 metal(0) complexes stabilized by phosphorus and carbon donor ligands, Synthesis of Nitrogen-containing Molecules via Transition Metal-Catalyzed Reactions on Isoxazoles, Anthraniils and Benzoisoxazoles, and more. Contains contributions from leading authorities in the field of organometallic chemistry Covers topics in organometallic synthesis, reactions, mechanisms, homogeneous catalysis, and more Informs and updates readers on the latest developments in the field Carefully edited to provide easy-to-read material

Pincer Metal Complexes Book

Pincer Metal Complexes


  • Author : Akshai Kumar
  • Publisher : Elsevier
  • Release Date : 2021-11-12
  • Genre: Science
  • Pages : 244
  • ISBN 10 : 9780128220924

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Pincer Metal Complexes Excerpt :

Pincer-Metal Complexes: Applications in Catalytic Dehydrogenation Chemistry provides an overview of pincer-metal catalytic systems that transform hydrocarbons and their derivatives from an synthetic and mechanistic point-of-view. This book provides thorough coverage of the operating mechanisms and dehydrogenation catalyst compatibility in both functionalized and unfunctionalized hydrocarbon systems. In addition, it includes success stories of pincer-metal systems, as well as current and future challenges. The book is an ideal reference for researchers practicing synthetic organic chemistry, inorganic chemistry, organometallic chemistry and catalysis in academia and industry. In recent years there has been a surge in the research on hydrocarbon dehydrogenation catalytic systems that are compatible with polar substituents. This helps facilitate formulation of tandem processes that are not limited to hydrocarbon transformation but also to hydrocarbon functionalization in a single pot. Covers applications of pincer-metal complexes in organic transformations Includes pincer-group 8 and 9 metal complexes for alkane dehydrogenations Features a discussion of pincer-metal complexes for the dehydrogenation of functionalized hydrocarbons and electro-catalytic transformations

The Privileged Pincer Metal Platform  Coordination Chemistry   Applications Book

The Privileged Pincer Metal Platform Coordination Chemistry Applications


  • Author : Gerard van Koten
  • Publisher : Springer
  • Release Date : 2015-08-27
  • Genre: Science
  • Pages : 374
  • ISBN 10 : 9783319229270

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The Privileged Pincer Metal Platform Coordination Chemistry Applications Excerpt :

The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics in pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors.

Organometallic Pincer Chemistry Book

Organometallic Pincer Chemistry


  • Author : Gerard van Koten
  • Publisher : Springer
  • Release Date : 2012-09-17
  • Genre: Science
  • Pages : 356
  • ISBN 10 : 9783642310812

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Organometallic Pincer Chemistry Excerpt :

Gerard van Koten: The Mono-anionic ECE-Pincer Ligand - a Versatile Privileged Ligand Platform: General Considerations.- Elena Poverenov, David Milstein: Non-Innocent Behavior of PCP and PCN Pincer Ligands of Late Metal Complexes.- Dean M. Roddick: Tuning of PCP Pincer Ligand Electronic and Steric Properties.- Gemma R. Freeman, J. A. Gareth Williams: Metal Complexes of Pincer Ligands: Excited States, Photochemistry, and Luminescence.- Davit Zargarian, Annie Castonguay, Denis M. Spasyuk: ECE-Type Pincer Complexes of Nickel.- Roman Jambor and Libor Dostál: The Chemistry of Pincer Complexes of 13 - 15 Main Group Elements.- Kálmán J. Szabo: Pincer Complexes as Catalysts in Organic Chemistry.- Jun-ichi Ito and Hisao Nishiyama: Optically Active Bis(oxazolinyl)phenyl Metal Complexes as Multi-potent Catalysts.- Anthony St. John, Karen I. Goldberg, and D. Michael Heinekey: Pincer Complexes as Catalysts for Amine Borane Dehydrogenation.- Dmitri Gelman and Ronit Romm: PC(sp3)P Transition Metal Pincer Complexes: Properties and Catalytic Applications.- Jennifer Hawk and Steve Craig: Physical Applications of Pincer Complexes.

Cyclometalation Reactions Book

Cyclometalation Reactions


  • Author : Iwao Omae
  • Publisher : Springer Science & Business Media
  • Release Date : 2014-01-23
  • Genre: Science
  • Pages : 208
  • ISBN 10 : 9784431546047

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Cyclometalation Reactions Excerpt :

This book provides a review of cyclometalation reactions and organometallic intramolecular-coordination five-membered ring products, the most active type of reactions in synthetic organic reactions and their products. Included is the discovery of intramolecular-coordination bonds in cyclometalation reactions and the characteristics of those reactions, as well as the reasons that their five-membered ring compounds are very easily synthesized through such reactions. In addition, the applications of cyclometalation reactions and five-membered ring products, synthetic applications, catalysts, and other products are described. These topics are of special interest for industrial researchers.

Organic Materials as Smart Nanocarriers for Drug Delivery Book

Organic Materials as Smart Nanocarriers for Drug Delivery


  • Author : Alexandru Mihai Grumezescu
  • Publisher : William Andrew
  • Release Date : 2018-03-26
  • Genre: Science
  • Pages : 768
  • ISBN 10 : 9780128136645

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Organic Materials as Smart Nanocarriers for Drug Delivery Excerpt :

Organic Materials as Smart Nanocarriers for Drug Delivery presents the latest developments in the area of organic frameworks used in pharmaceutical nanotechnology. An up-to-date overview of organic smart nanocarriers is explored, along with the different types of nanocarriers, including polymeric micelles, cyclodextrins, hydrogels, lipid nanoparticles and nanoemlusions. Written by a diverse range of international academics, this book is a valuable reference for researchers in biomaterials, the pharmaceutical industry, and those who want to learn more about the current applications of organic smart nanocarriers. Explores the most recent molecular- and structure-based applications of organic smart nanocarriers in drug delivery Highlights different smart nanocarriers and assesses their intricate organic structural properties for improving drug delivery Assesses how molecular organic frameworks lead to more effective drug delivery systems

Pincer and Pincer Type Complexes Book

Pincer and Pincer Type Complexes


  • Author : Kálmán J. Szabó
  • Publisher : John Wiley & Sons
  • Release Date : 2014-06-10
  • Genre: Science
  • Pages : 320
  • ISBN 10 : 9783527681334

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Pincer and Pincer Type Complexes Excerpt :

This new book on this hot topic summarizes the key achievements for the synthesis and catalytic applications of pincer and pincer-type complexes, providing readers with the latest research highlights. The editors have assembled an international team of leaders in the field, and their contributions focus on the application of various pincer complexes in modern organic synthesis and catalysis, such as C-C and C-X bond forming reactions, C-H bond functionalization, and the activation of small molecules, as well as asymmetric catalysis. A must-have for every synthetic chemist in both academia and industry intending to develop new catalysts and improved synthetic protocols.

Metal Ligand Co operativity Book

Metal Ligand Co operativity


  • Author : Gerard van Koten
  • Publisher : Springer Nature
  • Release Date : 2021-03-29
  • Genre: Science
  • Pages : 451
  • ISBN 10 : 9783030689162

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Metal Ligand Co operativity Excerpt :

This book provides researchers in the fields of organic chemistry, organometallic chemistry and homogeneous catalysis with an overview of significant recent developments in the area of metal-ligand cooperativity, with a focus on pincer architectures. The various contributions highlight the widespread impact of M–L co-operativity phenomena on modern organometallic chemistry and catalyst development. The development of efficient and selective catalytic transformations relies on the understanding and fine control of the various elementary reactions that constitutes a catalytic cycle. Co-operative ligands, which actively participate in bond making and bond breaking together to the metal they support, open up new avenues in this area. In particular, buttressing a weak or reactive metal-ligand bond by flanking coordinating arms in a pincer ligand design is proving a versatile strategy to access robust metal complexes that exhibit unusual and selective reactivity patterns.

Pincer Metal Complexes Book

Pincer Metal Complexes


  • Author : Akshai Kumar
  • Publisher : Elsevier
  • Release Date : 2021-11-26
  • Genre: Science
  • Pages : 244
  • ISBN 10 : 9780128220917

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Pincer Metal Complexes Excerpt :

Pincer-Metal Complexes: Applications in Catalytic Dehydrogenation Chemistry provides an overview of pincer-metal catalytic systems that transform hydrocarbons and their derivatives from an synthetic and mechanistic point-of-view. This book provides thorough coverage of the operating mechanisms and dehydrogenation catalyst compatibility in both functionalized and unfunctionalized hydrocarbon systems. In addition, it includes success stories of pincer-metal systems, as well as current and future challenges. The book is an ideal reference for researchers practicing synthetic organic chemistry, inorganic chemistry, organometallic chemistry and catalysis in academia and industry. In recent years there has been a surge in the research on hydrocarbon dehydrogenation catalytic systems that are compatible with polar substituents. This helps facilitate formulation of tandem processes that are not limited to hydrocarbon transformation but also to hydrocarbon functionalization in a single pot. Covers applications of pincer-metal complexes in organic transformations Includes pincer-group 8 and 9 metal complexes for alkane dehydrogenations Features a discussion of pincer-metal complexes for the dehydrogenation of functionalized hydrocarbons and electro-catalytic transformations

Modern Carbonylation Methods Book

Modern Carbonylation Methods


  • Author : László Kollár
  • Publisher : John Wiley & Sons
  • Release Date : 2008-06-25
  • Genre: Science
  • Pages : 383
  • ISBN 10 : 9783527621552

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Modern Carbonylation Methods Excerpt :

Comprehensively covering modern carbonylation chemistry, this book is an indispensable companion for all synthetic chemists working in industry and academia. This monograph contains everything there is to know from recent advances in the investigation of carbonylation catalysts, via coordination chemistry to the synthetic application of transition metal catalyzed carbonylations.

Alkane Functionalization Book

Alkane Functionalization


  • Author : Armando J. L. Pombeiro
  • Publisher : Wiley
  • Release Date : 2019-02-11
  • Genre: Science
  • Pages : 648
  • ISBN 10 : 9781119378808

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Alkane Functionalization Excerpt :

Presents state-of-the-art information concerning the syntheses of valuable functionalized organic compounds from alkanes, with a focus on simple, mild, and green catalytic processes Alkane Functionalization offers a comprehensive review of the state-of-the-art of catalytic functionalization of alkanes under mild and green conditions. Written by a team of leading experts on the topic, the book examines the latest research developments in the synthesis of valuable functionalized organic compounds from alkanes. The authors describe the various modes of interaction of alkanes with metal centres and examine theoxidative alkane functionalization upon C-O bond formation. They address the many types of mechanisms, discuss typical catalytic systems and highlight the strategies inspired by biological catalytic systems. The book also describes alkane functionalization upon C-heteroatom bond formation as well as oxidative and non-oxidative approaches. In addition, the book explores non-transition metal catalysts and metal-free catalytic systems and presents selected types of functionalization of sp3 C-H bonds pertaining to substrates other than alkanes. This important resource: Presents a guide to the most recent advances concerning the syntheses of valuable functionalized organic compounds from alkanes Contains information from leading experts on the topic Offers information on the catalytic functionalization of alkanes that allows for improved simplicity and sustainability compared to current multi-stage industrial processes Explores the challenges inherent with the application of alkanes as starting materials for syntheses of added value functionalized organic compounds Written for academic researchers and industrial scientists working in the fields of coordination chemistry, organometallic chemistry, catalysis, organic synthesis and green chemistry, Alkane Functionalization is an important resource for accessing the most up-to-date information available in the field of cata

The Chemistry of Organomagnesium Compounds  2 Volume Set Book

The Chemistry of Organomagnesium Compounds 2 Volume Set


  • Author : Zvi Rappoport
  • Publisher : John Wiley & Sons
  • Release Date : 2008-04-30
  • Genre: Science
  • Pages : 920
  • ISBN 10 : 9780470751862

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The Chemistry of Organomagnesium Compounds 2 Volume Set Excerpt :

Magnesium remains almost unique among the metals in its ability to react directly with a wide variety of compounds. This organic chemistry field has seen steady progress, and a volume on this topic is long overdue. In the tradition of the Patai Series this title treats all aspects of functional groups, containing chapters on the theoretical and computational foundations; on analytical and spectroscopic aspects with dedicated chapters on Mass Spectrometry, NMR, IR/UV, etc.; on reaction mechanisms; on applications in syntheses. Depending on the functional group there are also chapters on industrial use, on effects in biological and/or environmental systems. Since the area of Organomagnesium Chemistry continues to grow far beyond the classical Grignard Reagents, this is an essential resource to help the reader keep abreast of the latest developments.

Applied Homogeneous Catalysis with Organometallic Compounds Book

Applied Homogeneous Catalysis with Organometallic Compounds


  • Author : Boy Cornils
  • Publisher : John Wiley & Sons
  • Release Date : 2018-01-04
  • Genre: Science
  • Pages : 1872
  • ISBN 10 : 9783527328970

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Applied Homogeneous Catalysis with Organometallic Compounds Excerpt :

The completely revised third edition of this four-volume classic is fully updated and now includes such topics as as CH-activation and multicomponent reactions. It describes the most important reaction types, new methods and recent developments in catalysis. The internationally renowned editors and a plethora of international authors (including Nobel laureate R. Noyori) guarantee high quality content throughout the book. A "must read" for everyone in academia and industry working in this field.