The Chemistry of Pincer Compounds Book

The Chemistry of Pincer Compounds


  • Author : David Morales-Morales
  • Publisher : Elsevier
  • Release Date : 2011-08-11
  • Genre: Science
  • Pages : 466
  • ISBN 10 : 0080545157

GET BOOK
The Chemistry of Pincer Compounds Excerpt :

Pincer complexes are formed by the binding of a chemical structure to a metal atom with at least one carbon-metal bond. Usually the metal atom has three bonds to a chemical backbone, enclosing the atom like a pincer. The resulting structure protects the metal atom and gives it unique properties. The last decade has witnessed the continuous growth in the development of pincer complexes. These species have passed from being curiosity compounds to chemical chameleons able to perform a wide variety of applications. Their unique metal bound structures provide some of the most active catalysts yet known for organic transformations involving the activation of bonds. The Chemistry of Pincer Compounds details use of pincer compounds including homogeneous catalysis, enantioselective organic transformations, the activation of strong bonds, the biological importance of pincer compounds as potential therapeutic or pharmaceutical agents, dendrimeric and supported materials. * Describes the chemistry and applications of this important class of organometallic and coordination compounds * Covers the areas in which pincer complexes have had an impact * Includes information on more recent and interesting pincer compounds not just those that are well-known

Pincer Compounds Book

Pincer Compounds


  • Author : David Morales-Morales
  • Publisher : Elsevier
  • Release Date : 2018-04-11
  • Genre: Science
  • Pages : 754
  • ISBN 10 : 9780128129326

GET BOOK
Pincer Compounds Excerpt :

Pincer Compounds: Chemistry and Applications offers valuable state-of-the-art coverage highlighting highly active areas of research—from mechanistic work to synthesis and characterization. The book focuses on small molecule activation chemistry (particularly H2 and hydrogenation), earth abundant metals (such as Fe), actinides, carbene-pincers, chiral catalysis, and alternative solvent usage. The book covers the current state of the field, featuring chapters from renowned contributors, covering four continents and ranging from still-active pioneers to new names emerging as creative strong contributors to this fascinating and promising area. Over a decade since the publication of Morales-Morales and Jensen’s The Chemistry of Pincer Compounds (Elsevier 2007), research in this unique area has flourished, finding a plethora of applications in almost every single branch of chemistry—from their traditional application as very robust and active catalysts all the way to potential biological and pharmaceutical applications. Describes the chemistry and applications of this important class of organometallic and coordination compounds Includes contributions from global leaders in the field, featuring pioneers in the area as well as emerging experts conducting exciting research on pincer complexes Highlights areas of promising and active research, including small molecule activation, earth abundant metals, and actinide chemistry

Pincer Metal Complexes Book

Pincer Metal Complexes


  • Author : Akshai Kumar
  • Publisher : Elsevier
  • Release Date : 2021-11-26
  • Genre: Science
  • Pages : 244
  • ISBN 10 : 9780128220917

GET BOOK
Pincer Metal Complexes Excerpt :

Pincer-Metal Complexes: Applications in Catalytic Dehydrogenation Chemistry provides an overview of pincer-metal catalytic systems that transform hydrocarbons and their derivatives from an synthetic and mechanistic point-of-view. This book provides thorough coverage of the operating mechanisms and dehydrogenation catalyst compatibility in both functionalized and unfunctionalized hydrocarbon systems. In addition, it includes success stories of pincer-metal systems, as well as current and future challenges. The book is an ideal reference for researchers practicing synthetic organic chemistry, inorganic chemistry, organometallic chemistry and catalysis in academia and industry. In recent years there has been a surge in the research on hydrocarbon dehydrogenation catalytic systems that are compatible with polar substituents. This helps facilitate formulation of tandem processes that are not limited to hydrocarbon transformation but also to hydrocarbon functionalization in a single pot. Covers applications of pincer-metal complexes in organic transformations Includes pincer-group 8 and 9 metal complexes for alkane dehydrogenations Features a discussion of pincer-metal complexes for the dehydrogenation of functionalized hydrocarbons and electro-catalytic transformations

Organometallic Pincer Chemistry Book

Organometallic Pincer Chemistry


  • Author : Gerard van Koten
  • Publisher : Springer
  • Release Date : 2012-09-17
  • Genre: Science
  • Pages : 356
  • ISBN 10 : 9783642310812

GET BOOK
Organometallic Pincer Chemistry Excerpt :

Gerard van Koten: The Mono-anionic ECE-Pincer Ligand - a Versatile Privileged Ligand Platform: General Considerations.- Elena Poverenov, David Milstein: Non-Innocent Behavior of PCP and PCN Pincer Ligands of Late Metal Complexes.- Dean M. Roddick: Tuning of PCP Pincer Ligand Electronic and Steric Properties.- Gemma R. Freeman, J. A. Gareth Williams: Metal Complexes of Pincer Ligands: Excited States, Photochemistry, and Luminescence.- Davit Zargarian, Annie Castonguay, Denis M. Spasyuk: ECE-Type Pincer Complexes of Nickel.- Roman Jambor and Libor Dostál: The Chemistry of Pincer Complexes of 13 - 15 Main Group Elements.- Kálmán J. Szabo: Pincer Complexes as Catalysts in Organic Chemistry.- Jun-ichi Ito and Hisao Nishiyama: Optically Active Bis(oxazolinyl)phenyl Metal Complexes as Multi-potent Catalysts.- Anthony St. John, Karen I. Goldberg, and D. Michael Heinekey: Pincer Complexes as Catalysts for Amine Borane Dehydrogenation.- Dmitri Gelman and Ronit Romm: PC(sp3)P Transition Metal Pincer Complexes: Properties and Catalytic Applications.- Jennifer Hawk and Steve Craig: Physical Applications of Pincer Complexes.

The Privileged Pincer Metal Platform  Coordination Chemistry   Applications Book

The Privileged Pincer Metal Platform Coordination Chemistry Applications


  • Author : Gerard van Koten
  • Publisher : Springer
  • Release Date : 2015-08-27
  • Genre: Science
  • Pages : 374
  • ISBN 10 : 9783319229270

GET BOOK
The Privileged Pincer Metal Platform Coordination Chemistry Applications Excerpt :

The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics in pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors.

Copper I  Chemistry of Phosphines  Functionalized Phosphines and Phosphorus Heterocycles Book

Copper I Chemistry of Phosphines Functionalized Phosphines and Phosphorus Heterocycles


  • Author : Maravanji S. Balakrishna
  • Publisher : Elsevier
  • Release Date : 2019-04-25
  • Genre: Science
  • Pages : 442
  • ISBN 10 : 9780128156940

GET BOOK
Copper I Chemistry of Phosphines Functionalized Phosphines and Phosphorus Heterocycles Excerpt :

Copper(I) Complexes of Phosphines, Functionalized Phosphines and Phosphorus Heterocycles is a comprehensive guide to one of the most widely used and extensively studied metals: copper. The numerous practical applications of copper compounds are discussed, including homogeneous and heterogeneous catalysis and their use as fungicides, pesticides, pigments for paints, resins and glasses, and in high-temperature superconductors. The remarkable structural flexibility of simple copper(I) complexes, such as cuprous halides is covered, including numerous structural motifs that, when combined with different ligand systems, exhibit linear, trigonal planar or tetrahedral geometries. This work is an essential reference for inorganic and coordination chemists, as well as researchers working on catalysis, anticancer reagents, luminescence, fluorescence and photophysical aspects. Discusses the properties of copper and similarities to noble metals, such as their corrosion resistance, high thermal and electrical conductivity and rich coordination chemistry Includes the copper(I) coordination chemistry of tertiary phosphines, bisphosphines and phosphines containing other donor atoms and their potential application in catalysis, biosystems and photochemical areas Features a discussion of the rich photochemistry exhibited by some mixed-ligand copper(I) complexes (phosphines with heteroaromatic ligands) which can exhibit coprophilic interactions, photoluminescence and thermochromic properties

Pincer and Pincer Type Complexes Book

Pincer and Pincer Type Complexes


  • Author : Kálmán J. Szabó
  • Publisher : John Wiley & Sons
  • Release Date : 2014-06-10
  • Genre: Science
  • Pages : 320
  • ISBN 10 : 9783527681334

GET BOOK
Pincer and Pincer Type Complexes Excerpt :

This new book on this hot topic summarizes the key achievements for the synthesis and catalytic applications of pincer and pincer-type complexes, providing readers with the latest research highlights. The editors have assembled an international team of leaders in the field, and their contributions focus on the application of various pincer complexes in modern organic synthesis and catalysis, such as C-C and C-X bond forming reactions, C-H bond functionalization, and the activation of small molecules, as well as asymmetric catalysis. A must-have for every synthetic chemist in both academia and industry intending to develop new catalysts and improved synthetic protocols.

Advances in Organometallic Chemistry and Catalysis Book

Advances in Organometallic Chemistry and Catalysis


  • Author : Armando J. L. Pombeiro
  • Publisher : John Wiley & Sons
  • Release Date : 2013-10-11
  • Genre: Science
  • Pages : 736
  • ISBN 10 : 9781118742891

GET BOOK
Advances in Organometallic Chemistry and Catalysis Excerpt :

A contemporary compilation of recent achievements inorganometallic chemistry The prestigious International Conference on OrganometallicChemistry (ICOMC) was launched in 1963, providing a forum forresearchers from around the world to share their findings andexplore new paths to advance our knowledge and application oforganometallic chemistry. The 25th ICOMC, held in Lisbon in 2012,gathered more than 1,200 participants from 54 countries. Thisvolume celebrates the 25th Silver Edition and the 50th Gold Year ofthe ICOMC. Featuring contributions from invited 25th ICOMC speakers,Advances in Organometallic Chemistry and Catalysishighlights recent achievements and new and emerging areas ofresearch in the field. Its seven sections cover: Activation and Functionalization of Carbon Single Bonds andSmall Molecules Organometallic Synthesis and Catalysis Organometallic Polymerization Catalysis Organometallic Polymers and Materials Organometallic Chemistry and Sustainable Energy Bioorganometallic Chemistry Organometallic Electrochemistry Chapters discuss fundamental underlying concepts, offerillustrative examples and cases, and explore future avenues forcontinued research. Readers will discover basic principles andproperties of organometallic compounds, reaction mechanisms, anddetailed descriptions of current applications. Collectively, thesechapters underscore the versatility, richness, and potential ofmodern organometallic chemistry, including its interrelationshipswith other scientific disciplines. All the contributions are extensively referenced, providing agateway to the most important original research papers and reviewsin organometallic chemistry. Presenting a contemporaryunderstanding of organometallic chemistry and its manyapplications, Advances in Organometallic Chemistry andCatalysis is recommended for all researchers in the field, fromstudents to advanced investigators.

Organophosphorus Chemistry Book

Organophosphorus Chemistry


  • Author : John C. Tebby
  • Publisher : Royal Society of Chemistry
  • Release Date : 2018-04-13
  • Genre: Science
  • Pages : 440
  • ISBN 10 : 9781788011679

GET BOOK
Organophosphorus Chemistry Excerpt :

Coverage in this annual review of the literature presents a comprehensive and critical survey of the vast field of study involving organophosphorus compounds. From phosphines and related P-C bonded compounds through tervalent phosphorus acid derivatives, phosphine chalcogenides, and recent developments in green synthetic approaches in organophosphorus chemistry, the volume reflects established and current interests in the area. With an emphasis on interdisciplinary content, this book is aimed at the worldwide organic chemistry and engineering research communities.

The Chemistry of Organomagnesium Compounds  2 Volume Set Book

The Chemistry of Organomagnesium Compounds 2 Volume Set


  • Author : Zvi Rappoport
  • Publisher : John Wiley & Sons
  • Release Date : 2008-04-30
  • Genre: Science
  • Pages : 920
  • ISBN 10 : 9780470751862

GET BOOK
The Chemistry of Organomagnesium Compounds 2 Volume Set Excerpt :

Magnesium remains almost unique among the metals in its ability to react directly with a wide variety of compounds. This organic chemistry field has seen steady progress, and a volume on this topic is long overdue. In the tradition of the Patai Series this title treats all aspects of functional groups, containing chapters on the theoretical and computational foundations; on analytical and spectroscopic aspects with dedicated chapters on Mass Spectrometry, NMR, IR/UV, etc.; on reaction mechanisms; on applications in syntheses. Depending on the functional group there are also chapters on industrial use, on effects in biological and/or environmental systems. Since the area of Organomagnesium Chemistry continues to grow far beyond the classical Grignard Reagents, this is an essential resource to help the reader keep abreast of the latest developments.

Advances in Bioorganometallic Chemistry Book

Advances in Bioorganometallic Chemistry


  • Author : Toshikazu Hirao
  • Publisher : Elsevier
  • Release Date : 2018-11-30
  • Genre: Science
  • Pages : 472
  • ISBN 10 : 9780128141984

GET BOOK
Advances in Bioorganometallic Chemistry Excerpt :

Advances in Bioorganometallic Chemistry examines the synthesis, structure and reactivity of bioorganometallics, their pharmaceutical applications, hydrogenase, vitamin B12-like systems, and metalloproteins. It is written by the top researchers in the field and compiled by editors Toshikazu Hirao and Toshiyuki Moriuchi. Developments in this new field of bioorganometallic chemistry, a hybrid between biology and organometallic chemistry, happen very quickly and this comprehensive reference offers the latest research and findings in the field. The book features a discussion of the synthesis, structure, and reactivity of bioorganometallics, and an examination of hydrogenase-like systems, which were designed to demonstrate catalytic activities and functional properties. Advances in Bioorganometallic Chemistry also includes a discussion of bioorganometallics as they relate to medicinal chemistry, specifically applications of metalloproteins, metalloenzymes, and applications in bioimaging. The book concludes with coverage of vitamin B12-like systems, including the latest developments in derivatives designed to perform bio-inspired catalytic reactions. This work is a valuable resource for chemists working in organometallic chemistry and biology, including biochemists, bioorganic chemists, bioinorganic chemists, as well as pharmaceutical scientists, medicinal chemists, and students studying in these areas. Representative authors: R. H. Fish, T. Moriuchi, T. Hirao, H.-B. Kraatz, H. Takaya, T. P. Curran, G. van Koten. E. Rosenberg, J. M. Lynam, C. G. Hartinger, U. Schatzschneider, G. S. Smith, R. Alberto, S. Takenaka, T. Ihara, T. Hayashi, T. Ueno, P. Schollhammer, Y. Shomura, Y. Hisaeda, H. Shimakoshi, B. Kräutler Provides a balanced overview of the latest research in the field of bioorganometallic chemistry, drawing together the top researchers from around the world Covers topics in the areas of synthesis, reactivity, hydrogenase-like systems, medicinal chemistry, applicatio

Organophosphorus Chemistry Book

Organophosphorus Chemistry


  • Author : David W Allen
  • Publisher : Royal Society of Chemistry
  • Release Date : 2019-04-10
  • Genre: Reference
  • Pages : 439
  • ISBN 10 : 9781788014991

GET BOOK
Organophosphorus Chemistry Excerpt :

This annual review of the literature presents a comprehensive and critical survey of the vast field of study involving organophosphorus compounds, from phosphines and related P-C bonded compounds to phosphorus acids, phosphine chalcogenides and nucleotides. The Editors have added to the content with a timely chapter on the recent developments in green synthetic approaches in organophosphorus chemistry to reflect current interests in the area. With an emphasis on interdisciplinary content, this book is aimed at the worldwide organic chemistry and engineering research communities.

Iridium Complexes in Organic Synthesis Book

Iridium Complexes in Organic Synthesis


  • Author : Luis A. Oro
  • Publisher : John Wiley & Sons
  • Release Date : 2008-12-03
  • Genre: Science
  • Pages : 424
  • ISBN 10 : 9783527623082

GET BOOK
Iridium Complexes in Organic Synthesis Excerpt :

Ranging from hydrogenation to hydroamination, cycloadditions and nanoparticles, this first handbook to comprehensively cover the topic of iridium in synthesis discusses the important advances in iridium-catalyzed reactions, namely the use of iridium complexes in enantioselective catalysis. A must for organic, complex and catalytic chemists, as well as those working with/on organometallics.

Ruthenium in Catalysis Book

Ruthenium in Catalysis


  • Author : Pierre H. Dixneuf
  • Publisher : Springer
  • Release Date : 2014-10-18
  • Genre: Science
  • Pages : 401
  • ISBN 10 : 9783319084824

GET BOOK
Ruthenium in Catalysis Excerpt :

The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics in pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors.

Modern Carbonylation Methods Book

Modern Carbonylation Methods


  • Author : László Kollár
  • Publisher : John Wiley & Sons
  • Release Date : 2008-06-25
  • Genre: Science
  • Pages : 383
  • ISBN 10 : 9783527621552

GET BOOK
Modern Carbonylation Methods Excerpt :

Comprehensively covering modern carbonylation chemistry, this book is an indispensable companion for all synthetic chemists working in industry and academia. This monograph contains everything there is to know from recent advances in the investigation of carbonylation catalysts, via coordination chemistry to the synthetic application of transition metal catalyzed carbonylations.